稀(xi)(xi)土(tu)加(jia)人能(neng)(neng)(neng)(neng)使(shi)(shi)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)開始(shi)轉(zhuan)變溫(wen)度(du)(du)(du) (MI點(dian))升高(gao)(gao)(gao),研究得知(zhi),稀(xi)(xi)土(tu)加(jia)入(ru)能(neng)(neng)(neng)(neng)使(shi)(shi)從點(dian)升高(gao)(gao)(gao)100c,這就促使(shi)(shi)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)可在(zai)較(jiao)高(gao)(gao)(gao)的(de)溫(wen)度(du)(du)(du)下(xia)轉(zhuan)變,也有(you)(you)利于(yu)位(wei)錯(cuo)(cuo)(cuo)(cuo)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)的(de)形(xing)(xing)(xing)成(cheng)(cheng)。因(yin)為(wei)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)亞結構形(xing)(xing)(xing)成(cheng)(cheng)應(ying)當(dang)決(jue)(jue)定(ding)于(yu)不均(jun)勻切(qie)(qie)變方式—滑(hua)移(yi)形(xing)(xing)(xing)成(cheng)(cheng)位(wei)錯(cuo)(cuo)(cuo)(cuo)、孿生(sheng)形(xing)(xing)(xing)成(cheng)(cheng)孿晶。Thomas(8]認為(wei),成(cheng)(cheng)分(fen)(fen)和(he)溫(wen)度(du)(du)(du)決(jue)(jue)定(ding)滑(hua)移(yi)和(he)孿生(sheng)的(de)臨界分(fen)(fen)切(qie)(qie)應(ying)力(li),因(yin)而(er)(er)決(jue)(jue)定(ding)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)亞結構的(de)形(xing)(xing)(xing)態。在(zai)成(cheng)(cheng)分(fen)(fen)相同(tong)的(de)情況下(xia),轉(zhuan)變溫(wen)度(du)(du)(du)起主(zhu)(zhu)要(yao)作(zuo)用(yong),圖5一(yi)26為(wei)溫(wen)度(du)(du)(du)對(dui)滑(hua)移(yi)和(he)孿生(sheng)臨界分(fen)(fen)切(qie)(qie)應(ying)力(li)影(ying)響(xiang)的(de)示意圖。說明(ming)K點(dian)高(gao)(gao)(gao)時(shi),由于(yu)滑(hua)移(yi)的(de)臨界分(fen)(fen)切(qie)(qie)應(ying)力(li)較(jiao)低(di)(di)而(er)(er)形(xing)(xing)(xing)成(cheng)(cheng)位(wei)錯(cuo)(cuo)(cuo)(cuo)型(xing)條狀馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti),稀(xi)(xi)土(tu)一(yi)硼(peng)提高(gao)(gao)(gao)了鋼的(de)M.點(dian),必然(ran)導致(zhi)滑(hua)移(yi)臨界分(fen)(fen)切(qie)(qie)應(ying)力(li)減(jian)小,使(shi)(shi)轉(zhuan)變組織中位(wei)錯(cuo)(cuo)(cuo)(cuo)型(xing)板(ban)(ban)條馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)比(bi)例增加(jia)。此外,奧(ao)氏(shi)(shi)(shi)體(ti)層錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)也是影(ying)響(xiang)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)形(xing)(xing)(xing)態的(de)另一(yi)主(zhu)(zhu)要(yao)因(yin)素,奧(ao)氏(shi)(shi)(shi)體(ti)層錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)越低(di)(di),僅生(sheng)成(cheng)(cheng)板(ban)(ban)條狀馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)的(de)溫(wen)度(du)(du)(du)越低(di)(di)[9]r淬(cui)火時(shi)越有(you)(you)利于(yu)板(ban)(ban)條狀馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)的(de)形(xing)(xing)(xing)成(cheng)(cheng)。稀(xi)(xi)土(tu)能(neng)(neng)(neng)(neng)降低(di)(di)奧(ao)氏(shi)(shi)(shi)體(ti)的(de)層錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)(7,10]。因(yin)此能(neng)(neng)(neng)(neng)促使(shi)(shi)孿晶型(xing)向(xiang)位(wei)錯(cuo)(cuo)(cuo)(cuo)型(xing)轉(zhuan)變,使(shi)(shi)淬(cui)火組織中板(ban)(ban)條馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)數量(liang)增加(jia)。層錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)對(dui)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)的(de)影(ying)響(xiang)較(jiao)為(wei)復(fu)雜,隨鋼種(zhong)而(er)(er)異,不一(yi)定(ding)降低(di)(di)層錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)就能(neng)(neng)(neng)(neng)促進(jin)位(wei)錯(cuo)(cuo)(cuo)(cuo)馬(ma)(ma)(ma)(ma)(ma)(ma)(ma)氏(shi)(shi)(shi)體(ti)形(xing)(xing)(xing)成(cheng)(cheng)。且目前的(de)實驗手段(duan)還無法(fa)測定(ding)成(cheng)(cheng)分(fen)(fen)較(jiao)為(wei)復(fu)雜鋼種(zhong)的(de)位(wei)錯(cuo)(cuo)(cuo)(cuo)能(neng)(neng)(neng)(neng)。
B是一個促(cu)進(jin)鋼(gang)種成分偏析(xi)元素,不會象稀(xi)土那(nei)樣可促(cu)進(jin)成分均勻化,所以 B的加人不會促(cu)進(jin)位錯馬氏(shi)體(ti)(ti)量增加。馬氏(shi)體(ti)(ti)相變(bian)屬非擴(kuo)散型相變(bian),但它(ta)仍要通(tong)過形核長(chang)大方式進(jin)行。馬氏(shi)體(ti)(ti)晶核不是在母(mu)相中均勻分布(bu)的,而是在母(mu)相中某些(xie)特定區域,如位錯、層錯晶界這些(xie)晶體(ti)(ti)缺陷(xian)(xian)地(di)方先形核。由(you)于在晶體(ti)(ti)缺陷(xian)(xian)處偏聚和(he)M23 (CB)6這類(lei)固(gu)溶(rong)翻(fan)的析(xi)出,可作為(wei)馬氏(shi)體(ti)(ti)核坯,促(cu)使馬氏(shi)體(ti)(ti)細化。
RE一B復(fu)合變(bian)質處理,取兩者優點,B對馬氏體(ti)(ti)(ti)的(de)細(xi)化(hua)和稀土促進馬氏體(ti)(ti)(ti)亞結構位(wei)錯化(hua)。因而獲得了細(xi)小(xiao)的(de)位(wei)錯馬氏體(ti)(ti)(ti)為主的(de)馬氏體(ti)(ti)(ti)鋼(gang),使性能獲得改善(shan)。
(5)殘留奧氏體
對(dui)薄膜試(shi)樣進行(xing)觀察時發現(xian)經 RE或RE一(yi)B復合變(bian)質(zhi)(zhi)處理的(de)e一(yi) Mn鑄鋼(gang)(gang)和(he)Cr一(yi)Mn一(yi)Si鑄鋼(gang)(gang)組織中(zhong),馬氏(shi)(shi)(shi)體(ti)板(ban)(ban)條間(jian)有(you)一(yi)層(ceng)厚(hou)度約(yue)數百x 10-8cm的(de)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)薄膜,在(zai)(zai)明場下呈(cheng)暗色,暗場下呈(cheng)光亮色,經選區電(dian)子(zi)衍射(she)證實這(zhe)層(ceng)薄膜確為殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)、 并發現(xian)在(zai)(zai)不同的(de)淬火(huo)溫度下殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)里(li)也不一(yi)樣。用X射(she)線衍射(she)儀(yi)對(dui)復合變(bian)質(zhi)(zhi)處理的(de)Si一(yi)Mn鋼(gang)(gang)和(he)Cr 一(yi)Mn一(yi)Si鋼(gang)(gang)淬火(huo)/回火(huo)試(shi)樣進行(xing)殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)里(li)測定,變(bian)質(zhi)(zhi)處理能(neng)促進殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)薄膜在(zai)(zai)馬氏(shi)(shi)(shi)體(ti)板(ban)(ban)條間(jian)形成。眾所(suo)周知,奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)是一(yi)個韌性(xing)相組織,當裂紋(wen)穿(chuan)越殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)薄膜時,現(xian),有(you)助(zhu)于(yu)馬氏(shi)(shi)(shi)體(ti)鋼(gang)(gang)鑄鋼(gang)(gang)韌性(xing)增(zeng)加。要消耗(hao)更大的(de)能(neng)量。故(gu)殘(can)(can)留(liu)奧(ao)(ao)(ao)氏(shi)(shi)(shi)體(ti)薄膜的(de)出
稀土復合變質處理使中碳低合金鋼淬火組織中殘留奧氏體增加,其主要原因是由于稀土復合變質處理細化了晶粒,減小了枝晶間成分偏析,在奧氏體化溫度下,合金元素能充分溶人奧氏體,使奧氏體穩定性增加,馬氏體轉變區部分降至室溫以下的結果。耐磨鋼
